So what we have here is aggregate initialization covered in section 8.5.1
of the draft C++ standard and it says:
An aggregate is an array or a class [...]
and:
When an aggregate is initialized by an initializer list, as specified
in 8.5.4, the elements of the initializer list are taken as
initializers for the members of the aggregate, in increasing subscript
or member order. Each member is copy-initialized from the
corresponding initializer-clause [...]
Although it seems reasonable that side effects from initializing each member of the aggregate should be sequenced before the next, since each element in the initializer list is a full expression. The standard does not actually guarantee this we can see this from defect report 1343 which says:
The current wording does not indicate that initialization of a non-class object is a full-expression, but presumably should do so.
and also notes:
Aggregate initialization could also involve more than one full-expression, so the limitation above to “initialization of a non-class object” is not correct.
and we can see from a related std-discussion topic Richard Smith says:
[intro.execution]p10: "A full-expression is an expression that is not
a subexpression of another expression. [...] If a language construct
is defined to produce an implicit call of a function, a use of the
language construct is considered to be an expression for the purposes
of this definition."
Since a braced-init-list is not an expression, and in this case it
does not result in a function call, 5 and s.i are separate
full-expressions. Then:
[intro.execution]p14: "Every value computation and side effect
associated with a full-expression is sequenced before every value
computation and side effect associated with the next full-expression
to be evaluated."
So the only question is, is the side-effect of initializing s.i
"associated with" the evaluation of the full-expression "5"? I think
the only reasonable assumption is that it is: if 5 were initializing a
member of class type, the constructor call would obviously be part of
the full-expression by the definition in [intro.execution]p10, so it
is natural to assume that the same is true for scalar types.
However, I don't think the standard actually explicitly says this
anywhere.
So this is currently not specified by the standard and can not be relied upon, although I would be surprised if an implementation did not treat it the way you expect.
For a simple case like this something similar to this seems a better alternative:
constexpr int value = 13 ;
const int foo[2] = {value, value+42};
Changes In C++17
The proposal P0507R0: Core Issue 1343: Sequencing of non-class initialization clarifies the full-expression point brought up here but does not answer the question about whether the side-effect of initialization is included in the evaluation of the full-expression. So it does not change that this is unspecified.
The relevant changes for this question are in [intro.execution]:
A constituent expression is defined as follows:
(9.1) — The constituent expression of an expression is that expression.
(9.2) — The constituent expressions of a braced-init-list or of a (possibly parenthesized) expression-list are the
constituent expressions of the elements of the respective list.
(9.3) — The constituent expressions of a brace-or-equal-initializer of the form = initializer-clause are the
constituent expressions of the initializer-clause.
[ Example:
struct A { int x; };
struct B { int y; struct A a; };
B b = { 5, { 1+1 } };
The constituent expressions of the initializer used for the initialization of b are 5 and 1+1. —end example ]
and [intro.execution]p12:
A full-expression is
(12.1) — an unevaluated operand (Clause 8),
(12.2) — a constant-expression (8.20),
(12.3) — an init-declarator (Clause 11) or a mem-initializer (15.6.2), including the constituent expressions of the
initializer,
(12.4) — an invocation of a destructor generated at the end of the lifetime of an object other than a temporary
object (15.2), or
(12.5) — an expression that is not a subexpression of another expression and that is not otherwise part of a
full-expression.
So in this case both 13
and foo[0] + 42
are constituent expression which are part of a full-expression. This is a break from the analysis here which posited that they would each be their own full-expressions.
Changes In C++20
The Designated Initialization proposal: P0329 contains the following addition which seems to make this well defined:
Add a new paragraph to 11.6.1 [dcl.init.aggr]:
The initializations of the elements of the aggregate are evaluated in the element order. That is,
all value computations and side effects associated with a given element are sequenced before those of any element that follows it in order.
We can see this is reflected in the latest draft standard.